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0-Keto esters, silicon derivatives

Oxetanes 205 are produced with a high degree of stereoselectivity when an allylsilane with bulky substituents at the silicon center reacts with a-keto ester in the presence of TiCLj (equation 168). It is interesting to note that tetrahydrofuran derivatives are obtained at high temperature297. [Pg.1849]


See other pages where 0-Keto esters, silicon derivatives is mentioned: [Pg.7]    [Pg.136]    [Pg.423]   
See also in sourсe #XX -- [ Pg.7 , Pg.30 ]

See also in sourсe #XX -- [ Pg.7 , Pg.30 ]

See also in sourсe #XX -- [ Pg.7 , Pg.30 ]




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3-Keto esters

Ester derivation

Ester derivatives

Silicon derivatives

Silicon esters

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