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Keggin-type polyanions

Figure 1. Ball and stick (A) and polyhedral (B) representation of the monosubstituted Keggin-type polyanion [XWl lM(L)039]n-. Reprinted from J. Mol. Catal. A Chem. 262, Kholdeeva, O. A. Maksimovskaya, R. L, 7-24, Copyright (2007), with permission from Elsevier. Figure 1. Ball and stick (A) and polyhedral (B) representation of the monosubstituted Keggin-type polyanion [XWl lM(L)039]n-. Reprinted from J. Mol. Catal. A Chem. 262, Kholdeeva, O. A. Maksimovskaya, R. L, 7-24, Copyright (2007), with permission from Elsevier.
Figure 44 Examples of heteropolyanions (A) Keggin-type polyanion, for example 0 -PW,2O403-, (B) Dawson-type polyanion, for example P2Wn80626 (C) disubstituted polyanion, for example >-SiW,oFe204o,0. Taken from Ref. [216]. Reproduced by permission of The Royal Society of Chemistry. Figure 44 Examples of heteropolyanions (A) Keggin-type polyanion, for example 0 -PW,2O403-, (B) Dawson-type polyanion, for example P2Wn80626 (C) disubstituted polyanion, for example >-SiW,oFe204o,0. Taken from Ref. [216]. Reproduced by permission of The Royal Society of Chemistry.
Most phosphatotungstates belong to three structural types. The first type is that of the Keggin polyanion o-[PWi204o] [39] (Figure 5.10). Its structure is analogous to... [Pg.251]


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See also in sourсe #XX -- [ Pg.111 ]




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Keggin-type

Polyanion

Polyanionic

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