Julolidine, reduction

Julolidine has been prepared by the reaction of trimethylene chlorobromide with formanilide, aniline, methylaniline, and tetrahydroquinoline by the reduction of 8,10-diketojuloli-... 

The lithium-propylamine reducing system has been found capable of reducing julolidine to a mixture of enamines377. Selective reduction of lactams with... 

Julolidine has been prepared by the reaction of tiimethylene chlorobromide with formanilide, aniline, methylaniline, and tetrahydroquinoline by the reduction of 8,10-diketojulolidine by the intramolecular condensation of N-C-y-bromopropyl)-tetrahydroquinoline and by dehydration of N-Cy-hydroxy-propyl)-tetrahydroquinoline or di-(7-hydroxypropyl)-aniline with phosphorus pentoxide. ... 

Scheme 15.120 En antioselective synthesis of julolidine derivatives via a chiral acid-catalyzed imine formation, organocatalyzed [4+2] cyclization, and Au-catalyzed hydroamination, followed by reduction.

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