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Jahn-Teller theorem pseudo

Bader 46) considered the implications of the pseudo Jahn-Teller theorem for this and deduced that the bond stretching E mode would be the most likely reaction coordinate, and one can see from Fig. 10 that this would lead to the required products if continued to dissociation. [Pg.116]

The above account of copper(II) stereochemistry and electronic properties (Sections 53,4 and 53.4.4) establishes the uniqueness of the regular octahedral (and trigon octahedral) stereochemistries and the novel temperature variability of this stereochemistry (Sections 53.4.2.li and x) and the corresponding ESR spectra. " In order to understand these properties it is necessary to examine the Jahn-Teller theorem in a little more detail, as the consequences of this theorem extend beyond the above two topics and will cover the following (i) temperature variable (fluxional) copper(II) pseudo stereochemistries (ii) non temperature variable, static copper(II) stereochemistries (iii) the plasticity effect and varying tetragonal distortions (iv) the second order Jahn-Teller effect " and (v) the cooperative" and noncooperative " Jahn-Teller effects. For this reason the application of the Jahn-Teller theorem to the coordination chemistry of the copper(II) ion will be described" " and extended to the above topics." " " ... [Pg.5563]


See other pages where Jahn-Teller theorem pseudo is mentioned: [Pg.534]    [Pg.690]    [Pg.519]    [Pg.324]    [Pg.10]    [Pg.7]    [Pg.333]    [Pg.4]    [Pg.52]    [Pg.921]   
See also in sourсe #XX -- [ Pg.469 ]




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