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Jahn-Teller effect construction

The general principles for the construction of the vibronic Hamiltonian and the symmetry selection rules are the same as indicated above and discussed in more detail in Chapter 7. The previous distinction between trigonal and tetragonal point groups does not play a role, and the first-order coupling is always accomplished by doubly degenerate (e) vibrational modes. In an analogous notation as in Eq. (3), the Hamiltonian for the linear (E + A) (g) e pseudo-Jahn-Teller effect is found to... [Pg.444]

The effective-mode transformation described here is closely related to earlier works which led to the construction of so-called interaction modes [75, 76] or cluster modes [77, 78] in Jahn-Teller systems. The approach of Refs. [54,55,72] generalizes these earlier analyses to the generic form - independent of particular symmetries - of the linear vibronic coupling Hamiltonian Eq. (8). [Pg.196]


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See also in sourсe #XX -- [ Pg.461 , Pg.462 , Pg.463 , Pg.464 , Pg.465 , Pg.466 , Pg.467 , Pg.468 , Pg.469 , Pg.470 , Pg.471 ]

See also in sourсe #XX -- [ Pg.461 , Pg.462 , Pg.463 , Pg.464 , Pg.465 , Pg.466 , Pg.467 , Pg.468 , Pg.469 , Pg.470 , Pg.471 ]




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