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Its Hydridomethyl Tautomer

The crystalline compound [OsjH2(CH2)(CO),o], in solution exists as a mixture of methyl and methylene tautomers. A fully equilibrated sample in cyclohexane displays IR bands at 2126(w), 2108(vw), 2089(s), 2067(sh), 2059(vs), 2021 (vs), 2005(vs), 2005(sh), 1985(m), and 1978(m)cm . The HNMR spectrum in chloroform-d exhibits four multiplets of equal [Pg.207]

These procedures are modifications of previously published syntheses (ref. 9). [Pg.208]

Shriver, The Manipulation of Air-Sensitive Compounds, McGraw-Hill, New York, 1969, pp. 145-146. [Pg.208]


See other pages where Its Hydridomethyl Tautomer is mentioned: [Pg.206]    [Pg.206]   


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Tautomer

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