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Isotope effects on acidity

Secondary deuterium isotope effects on acidities in solution 134... [Pg.123]

Salomaa, P., Hakala, R., Vesala, S., and Aalto, T., 1969, Solvent deuterium isotope effects on acid-base reactions. Part III. Relative acidity constants of inorganic oxyacids in light and heavy water. Kinetic applications Acta Chemica Scandinavica, v. 23, p. 2116-2126. [Pg.459]

C.L. Perrin, Secondary equilibrium isotope effects on acidity, Adv. Phys. Organic Chem. 44 (2010), pp. 123-171. [Pg.163]

Some areas which are not covered are isotope effects on proton and deuterium exchange with solvent, for example, the water-hydronium ion system (Saunders et al., 1984), deuterium isotope effects on acid and base strength (Halevi et al., 1979), on amino acids (Petersen and Led, 1979) and on hydration of cobalt (II) (Saunders and Evilia, 1985). Solvent-dependent isotope effects on equilibria involving hydrogen bonds in carbohydrates and... [Pg.64]

Referring to Sec. II, where it was shown that isotopic substitution can significantly affect charge distribution, it seems unreasonable to attempt to deal with isotope effects on acid strength or other ionic... [Pg.129]

See other pages where Isotope effects on acidity is mentioned: [Pg.359]    [Pg.289]    [Pg.123]    [Pg.123]    [Pg.123]    [Pg.125]    [Pg.127]    [Pg.129]    [Pg.131]    [Pg.133]    [Pg.135]    [Pg.137]    [Pg.139]    [Pg.141]    [Pg.143]    [Pg.143]    [Pg.145]    [Pg.147]    [Pg.149]    [Pg.151]    [Pg.153]    [Pg.155]    [Pg.157]    [Pg.157]    [Pg.159]    [Pg.161]    [Pg.163]    [Pg.165]    [Pg.167]    [Pg.169]    [Pg.172]    [Pg.409]    [Pg.249]    [Pg.289]    [Pg.23]    [Pg.383]    [Pg.290]    [Pg.363]    [Pg.429]    [Pg.295]   
See also in sourсe #XX -- [ Pg.124 ]



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