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Isopropylthiomethyl ethers

Isopropyhhiomethyl ethers, ROCH2SCH(CHj)2. Methoxyethoxymethyl (MEM) ethers on reaction with 1 and 4-dimethylaminopyridine in CH2CI2 are converted into isopropylthiomethyl ethers. In the absence of DMAP, the MEM ether is cleaved to the free alcohol. Isopropylthiomethyl ethers can be cleaved to the alcohol under nonacidic conditions by silver nitrate and 2,6-lutidine. [Pg.57]


See other pages where Isopropylthiomethyl ethers is mentioned: [Pg.618]    [Pg.618]   
See also in sourсe #XX -- [ Pg.57 ]

See also in sourсe #XX -- [ Pg.57 ]




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