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Isodielectric universal solvent

As appears from the above, specific solvation of one component decreases equilibrium constants in comparison with equilibrium constants in isodielectric universal solvent. [Pg.536]

The reaction [9.104] also has been studied for isodielectric mixtures of alcohol-chlorobenzene with 8=20,2 (permittivity of pure n-propanol) and 8=17.1 (permittivity of pure n-butanol) to investigate flic relative effect of universal and specific solvation on the resolvation process. The mixtures were prepared by adding chlorobenzene to methanol, ethanol, and C1-C3 alcohol. Alcohol is a solvate-active component in these isodielectric solvents. K s data are given in Table 9.6. [Pg.545]


See also in sourсe #XX -- [ Pg.435 ]




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