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Isocyanides adducts, uranium

The analogous uranium(III) compounds also show unusual reactivity patterns. For example, addition of COT to (Cp )3U yields a mixed metallocene dimer (18) bridged by a COT ligand in this reaction, the (Cp )3U complex has effectively acted as a formal three-electron reductant (equation 3)." A variety of substituted (Cp )3U complexes form adducts with CO and CNR (isocyanides) - these are rare examples of actinide metals with r-acidic ligands." Paramagnetic uranium alkyl complexes are active in a range of catalytic processes." ... [Pg.3593]

Isoelectronic isocyanide ligands also undergo insertion into inanium-carbon or uranium-nitrogen bonds [227,228] to yield ri -iminoalkyl (11) and Ti -iminocarbamoyl (12) adducts ... [Pg.49]

See other pages where Isocyanides adducts, uranium is mentioned: [Pg.213]    [Pg.31]    [Pg.336]    [Pg.112]    [Pg.198]    [Pg.48]    [Pg.32]   


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Isocyanide adducts

Uranium adducts

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