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Isocyanide group biosynthesis

BIOSYNTHESIS OF THE ISOCYANIDE GROUP AND RELATED SUBSTITUENTS IN MARINE SPONGES... [Pg.349]

The same method has been applied in the synthesis of the western building block 1636 of vitamin B12, relevant to vitamin B12 biosynthesis. The original cyano group is reduced to an amino group, this is formylated, the resulting formamide is dehydrated with phosphoryl chloride forming the isocyanide, which is reductively cleaved [1221], For the dehydration of the formamide with phosphoryl chloride, l,8-bis(dimethylamino)naphthalene was chosen as an auxiliary base. [Pg.420]

See other pages where Isocyanide group biosynthesis is mentioned: [Pg.87]    [Pg.361]    [Pg.150]    [Pg.658]    [Pg.79]    [Pg.150]    [Pg.467]    [Pg.329]    [Pg.330]    [Pg.349]    [Pg.351]    [Pg.351]    [Pg.354]    [Pg.356]    [Pg.357]    [Pg.362]    [Pg.363]    [Pg.277]   
See also in sourсe #XX -- [ Pg.21 , Pg.349 ]

See also in sourсe #XX -- [ Pg.349 ]



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Isocyanide group

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