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Isocyanates, reaction with alkenes

Methylarsine, trifluoromethylarsine, and bis(trifluoromethyl)arsine [371-74-4] C2HAsF, are gases at room temperature all other primary and secondary arsines are liquids or solids. These compounds are extremely sensitive to oxygen, and ia some cases are spontaneously inflammable ia air (45). They readily undergo addition reactions with alkenes (51), alkynes (52), aldehydes (qv) (53), ketones (qv) (54), isocyanates (55), and a2o compounds (56). They also react with diborane (43) and a variety of other Lewis acids. Alkyl haUdes react with primary and secondary arsiaes to yield quaternary arsenic compounds (57). [Pg.336]

Woodward s synthesis, 4, 416-419 Chlorophyll b, 4, 382 Chlorophyll c, 4, 382 Chlorophyll d, 4, 382 Chlorophylls, 4, 378 biosynthesis reviews, 1, 99 structure, 4, 370 substituents reactions, 4, 402 Chloroporphyrin e6, 4, 404 Chloroprothixene pharmacology, 3, 942 Chloropyramine as antihistamine, 1, 177 Chloropyrifos synthesis, 2, 201 Chloropyrifos-ethyl as insecticide, 2, 516 Chloropyrifos-methyl as insecticide, 2, 516 Chloroquine, 1, 145 adsorption on nucleic acids, 1, 179 as antimalarial, 1, 173, 2, 517 Chloroquine, hydroxy-as antimalarial, 2, 517 Chlorosulfonyl isocyanate cycloaddition reactions with alkenes, azetidin-2-ones from, 7, 261 reactions... [Pg.577]

Thiobenzoyl isocyanate is widely used as a starting material for the syntheses of TAs 23-28 both in condensation with ethyl sodiocyanoacetate (86KGS3) and in [4 + 2]-cycloaddition reactions with alkenes and alkynes containing electron-donor groups (81CB2713 85ZC324) (Scheme 4). It is established that the rate of cycloaddition increases from alkenes to alkynes and with the electron-donor properties of substituents. [Pg.133]

Ketenes react with imines via [2+2]-cycloaddition to produce P-lactams.278 An example is the reaction of the acid chloride of phenylacetic acid with Proton Sponge to give ketene 340, which reacted with the tosyl imine shown and a quinuclidine catalyst to give a 65% yield of P-lactam 341, in 96% ee.229 A-Substituted isocyanates also undergo thermal [2+2]-cycloaddition reactions with alkenes, generating P-lactams.280... [Pg.981]

The cycloaddition of alkenes is quite general and has been extended to the formation of azanickelacycles 12 by using isocyanates instead of CO2 in the reaction with alkenes or 1,3-butadienes (Eq. 6). These... [Pg.9]

In a manner analogous to classic nitrile iinines, the additions of trifluoro-methylacetonitrile phenylimine occur regiospecifically with activated terminal alkenes but less selectively with alkynes [39], The nitnle imine reacts with both dimethyl fumarate and dimethyl maleate m moderate yields to give exclusively the trans product, presumably via epimenzation of the labile H at position 4 [40] (equation 42) The nitrile imine exhibits exo selectivities in its reactions with norbornene and norbornadiene, which are similar to those seen for the nitrile oxide [37], and even greater reactivity with enolates than that of the nitnle oxide [38, 41], Reactions of trifluoroacetomtrile phenyl imine with isocyanates, isothiocyanates, and carbodiimides are also reported [42]... [Pg.811]

There are actually three reactions called by the name Schmidt reaction, involving the addition of hydrazoic acid to carboxylic acids, aldehydes and ketones, and alcohols and alkenes. The most common is the reaction with carboxylic acids, illustrated above.Sulfuric acid is the most common catalyst, but Lewis acids have also been used. Good results are obtained for aliphatic R, especially for long chains. When R is aryl, the yields are variable, being best for sterically hindered compounds like mesi-toic acid. This method has the advantage over 18-13 and 18-14 that it is just one laboratory step from the acid to the amine, but conditions are more drastic. Under the acid conditions employed, the isocyanate is virtually never isolated. [Pg.1413]

Functionalization of Ni(MeCOCHCOMe)2 occurs in reactions with isocyanates, diethyl azodi-carboxylate and dimethyl acetylenedicarboxylate, which proceed by formal insertion of the methine C—H unit into the substrate multiple bonds to form respectively amides and ester-substituted hydrazines and alkenes. Similar additions of acetylacetone to these electrophiles is catalyzed by nickel acetylacetonate.217,218... [Pg.378]


See other pages where Isocyanates, reaction with alkenes is mentioned: [Pg.503]    [Pg.427]    [Pg.31]    [Pg.17]    [Pg.126]    [Pg.176]    [Pg.119]    [Pg.81]    [Pg.94]    [Pg.672]    [Pg.310]    [Pg.442]    [Pg.442]   
See also in sourсe #XX -- [ Pg.254 , Pg.255 ]




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Alkenes reaction with chlorosulfonyl isocyanate

Halogen isocyanates reactions with alkenes

Isocyanates reaction

Reaction with alkenes

Reaction with isocyanate

With isocyanates

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