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Isobutonium ions

Figure 19 The isobutonium ions. Values on the bottom of the structures correspond to relative energies (Mi) in kcal/mol. Figure 19 The isobutonium ions. Values on the bottom of the structures correspond to relative energies (Mi) in kcal/mol.
Comparison among -butonium and isobutonium ions allows for the interpretation of the effect of structural parameters on the basicity of these alkanes. A scale of basicity for a bonds of alkanes was proposed based on these results (82). [Pg.332]

A theoretical ab initio study of the interconversion of isobutonium ions has been carried out. The 1,1-trimethylene-l//-azulenium ion (202) has been prepared and its chemical behaviour has been shown to be different from that of its three-membered ring homologue. The solvolysis of l-[trans-2-(m- or / -substituted phenyl)... [Pg.553]


See other pages where Isobutonium ions is mentioned: [Pg.327]    [Pg.329]    [Pg.222]    [Pg.314]    [Pg.316]    [Pg.214]   


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