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Iron-TAML® catalysts

Collins, T. J. Khetan, S. K. Ryabov, A. D. Iron-TAML catalysts in green oxidation processes based on hydrogen peroxide. In Handbook of Green Chemistry, Anastas, P. T Crabtree, R. H. (eds.), Wiley-VCH Verlag GmbH and KgaA, Weinheim, 2009. [Pg.93]

If step III in Scheme 6 is ignored, a simplification is reached that has been demonstrated to be reasonable with certain substrates (see below). As a consequence, then the 1 catalysts should oxidize targeted reductants in accordance with Eq. (13) (here [Fe-TAML] is the total concentration of all TAML iron in solution). Eq. (13) implies that the catalysis by 1 mimics the steady-state oxidation by peroxidase enzymes, where Compound I is much more reactive than Compound II (55). [Pg.495]

See other pages where Iron-TAML® catalysts is mentioned: [Pg.156]    [Pg.160]    [Pg.156]    [Pg.160]    [Pg.487]    [Pg.202]    [Pg.505]    [Pg.86]    [Pg.84]    [Pg.472]    [Pg.516]    [Pg.66]    [Pg.55]    [Pg.296]    [Pg.296]    [Pg.45]    [Pg.160]    [Pg.161]    [Pg.87]    [Pg.88]   


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