Iron carbonyls containing S-donor ligands

Mononuclear Iron Carbonyls without Hydrocarbon Ligands 

Temperature- and field-dependent Mossbauer studies were performed on Fc3(SPh)6(CO)6 52. All Fe atoms are Fe(ll) with the two Fe(CO)3 units having low spin, while the central Fe(ll) is high spin (A= 2).  

In addition to these mononuclear complexes, the chemistry of the diiron compounds of the type FezlCOlel/t-SRlz, Fc2(CO)6( -ER)( -ER), [Fe2(CO)6( -ER)(/r-E)] (E = S, Se), and related complexes has been thoroughly examined. Since these compounds have Fe-Fe bonds, the reader is referred to Chapter 6.02. 

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Iron carbonyls containing S-donor ligands and cyanide or organic isocyanide ligands... 

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