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Iridium complexes reaction with sulfur dioxide

Scheme 15. The reactions of sulfur dioxide with dioxygen complexes of iridium. Scheme 15. The reactions of sulfur dioxide with dioxygen complexes of iridium.
The reaction of tra 3 -IrCl(CO)(PPh3)2 with carbon disulfide in the presence of NaBPli4 yields [(49)](BPli4) in which the S-donor ligand is the zwitterion S2C PPh3+. Sulfur dioxide is S-bonded to an iridium(I) atom in the trigonal bipyramidal complex IrH(PPh3)2(CO)(S02) in the related chloro complex (50), the Ir-S distance is 2.45 A. ... [Pg.1847]


See other pages where Iridium complexes reaction with sulfur dioxide is mentioned: [Pg.405]    [Pg.297]    [Pg.316]    [Pg.297]    [Pg.316]   
See also in sourсe #XX -- [ Pg.68 ]




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Dioxides, reactions

Iridium complexes reactions

Iridium complexes sulfur dioxide

Iridium complexes, reaction with

Iridium dioxide

Iridium reactions with

Reaction with sulfur dioxide

Sulfur complexes

Sulfur dioxide reactions

Sulfur dioxide, complexation with

Sulfur reaction with

With iridium

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