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Ionic-covalent transition short-range

Of much greater chemical significance is the short-range ionic-covalent transition, which marks the inevitable collapse of a purely ionic description at shorter distances. In LiF this transition is centered around RjJ) — 0.73 A, all but hidden under the... [Pg.60]

Figure 2.9 Variations of bond order (upper panel) and charge (lower panel) near the short-range ionic-covalent transition. Figure 2.9 Variations of bond order (upper panel) and charge (lower panel) near the short-range ionic-covalent transition.
Figure 2.19 -dependent variation of metal charge (gsc) in Sc—F, showing Req (vertical dashed line) and the nearby short-range ionic-covalent transition. [Pg.80]

Figure 2.10 The bonding NBO of LiF, showing short-range transition from ionic to covalent form. Figure 2.10 The bonding NBO of LiF, showing short-range transition from ionic to covalent form.
See other pages where Ionic-covalent transition short-range is mentioned: [Pg.52]    [Pg.60]    [Pg.61]    [Pg.64]    [Pg.80]    [Pg.167]    [Pg.235]    [Pg.98]    [Pg.235]    [Pg.341]    [Pg.557]    [Pg.98]   
See also in sourсe #XX -- [ Pg.52 , Pg.60 , Pg.61 , Pg.80 , Pg.86 , Pg.91 ]



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