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Iodide ligands equivalents

More recently, Chiu and coworkers have developed a Ni complex containing a tetradentate pyridine/NHC ligand (complex 18, Eq. 22) which catalyzes the Suzuki reaction at catalyst loadings between 1 and 3 mol% [56]. Aryl iodides, bromides, and chlorides with both electron-rich and -poor aryl rings were compatible. However, electronically poor or electronically neutral aryl bromides performed much better than did electron-rich aryl bromides. It was also found that the use of 2 equivalents of PPh3 was crucial to achieving high yields with aryl chlorides. [Pg.179]

The scope of the Heck and related coupling reactions was substantially broadened by the development, in the last few years, of palladium/ligand combinations which are effective with the cheap and readily available but less reactive aryl chlorides [86, 87] rather than the corresponding bromides or iodides. The process still generates one equivalent of chloride, however. Of interest in this context, therefore, is the report of a halide-free Heck reaction which employs an aromatic carboxylic anhydride as the arylating agent and requires no base or phosphine ligands [89]. [Pg.25]


See other pages where Iodide ligands equivalents is mentioned: [Pg.184]    [Pg.343]    [Pg.202]    [Pg.142]    [Pg.142]    [Pg.171]    [Pg.244]    [Pg.185]    [Pg.420]    [Pg.248]    [Pg.32]    [Pg.98]    [Pg.122]    [Pg.213]    [Pg.144]    [Pg.140]    [Pg.115]    [Pg.493]    [Pg.148]    [Pg.329]    [Pg.149]    [Pg.92]    [Pg.183]    [Pg.132]    [Pg.19]    [Pg.571]    [Pg.380]    [Pg.800]    [Pg.7]    [Pg.844]    [Pg.248]    [Pg.248]    [Pg.409]    [Pg.138]    [Pg.293]    [Pg.268]    [Pg.73]    [Pg.169]    [Pg.92]    [Pg.334]    [Pg.17]    [Pg.40]    [Pg.1060]    [Pg.1381]    [Pg.2803]    [Pg.4094]    [Pg.4099]    [Pg.4240]    [Pg.145]   
See also in sourсe #XX -- [ Pg.343 ]




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Iodide ligands

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