Intramolecular coordination, organomagnesium compounds

Intramolecular coordination in organomagnesium compounds is a common feature of their structures, and the subject has been reviewed.161 The diorganomagnesium adducts, MgR2(L) (R = methyl, ethyl L = tmeda, pmdta),... [Pg.89]

D. Intramolecular Coordination in Organomagnesium Compounds I. Complexes with Simple Ligands... [Pg.184]

The crystal packing of organomagnesium compounds has shown that intramolecular coordination is preferred over solvent coordination. These compounds have a tetrahedral geometry. The crystal structure of [MeO(CH2)4]aMg [Compound 27] indicates that the... [Pg.127]