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Intramolecular aryl-alkene coupling cascade

Scheme 3-36 Intramolecular tiryl-aryl as well as intra-intermolecular aryl-aryl and aryl-alkene coupling cascades [189]. Scheme 3-36 Intramolecular tiryl-aryl as well as intra-intermolecular aryl-aryl and aryl-alkene coupling cascades [189].
Scheme 8.49 Inter-intramolecular alkenyl-alkene and aryl-alkene coupling cascades involving C-H activation [1 1 5, 357d,e], A Pd(OAc)j, KjCOj, riBu NBr, DMF, 80°C, 24h. B Like A, but, 100°C for 7 and 21 days, respectively [115],... Scheme 8.49 Inter-intramolecular alkenyl-alkene and aryl-alkene coupling cascades involving C-H activation [1 1 5, 357d,e], A Pd(OAc)j, KjCOj, riBu NBr, DMF, 80°C, 24h. B Like A, but, 100°C for 7 and 21 days, respectively [115],...
In a narrower sense, this review covers intramolecular Mizoroki-Heck [1] reactions forming carbocycles [2] that is, the palladium-catalyzed intramolecular coupling of vinyl/aryl (pseudo-)halides with an alkene tethered by a hydrocarbon chain. Ring closures furnishing heterocycles are covered in Chapter 6 also beyond the scope of this chapter are the domino/cascade or tandem (Chapter 8) and asymmetric processes (Chapters 12 and 16) dealing with formation of a carbocycle. [Pg.179]


See other pages where Intramolecular aryl-alkene coupling cascade is mentioned: [Pg.1123]    [Pg.1123]    [Pg.761]   
See also in sourсe #XX -- [ Pg.129 ]

See also in sourсe #XX -- [ Pg.129 ]




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Alkenes, intramolecular

Aryl coupling

Arylation intramolecular

Couplings alkenes

Intramolecular cascade

Intramolecular coupling

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