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Intervalence band contribution

It has recently been suggested by Hush (13) that the asymmetry on the high energy side of the C T ion intervalence band can be easily rationalized by including contributions from totally symmetric modes of the ion. Day (20) has interpreted the... [Pg.287]

From Equations (3) and (4), it is possible to calculate the free energy of resonance exchange from intervalence band data. This value of AG, can be compared to an experimental value that is derived from electrochemical data and knowledge of the free energy factors that contribute to... [Pg.236]

From these analyses, it can be seen that effective electronic communication may occur between the metal centers through the band states of the Ru metal core when a conjugated spacer is used to link the ferrocene moieties onto the particle surface, whereas saturated linkers diminish drastically the intervalence transfer at mixed valence. Additionally, the nanoparticle-mediated intervalence transfer appears to be primarily dominated by through-bond contributions rather than direct overlap between the metal centers. [Pg.202]

See other pages where Intervalence band contribution is mentioned: [Pg.280]    [Pg.162]    [Pg.570]    [Pg.328]    [Pg.116]    [Pg.36]    [Pg.222]    [Pg.165]    [Pg.174]    [Pg.116]    [Pg.709]    [Pg.125]    [Pg.201]    [Pg.480]    [Pg.495]    [Pg.245]   
See also in sourсe #XX -- [ Pg.288 , Pg.290 ]



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Intervalence band

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