Intermolecular Dihydrogen Bonding in Transition Metal Hydride Complexes

INTERMOLECULAR DIHYDROGEN BONDING IN TRANSITION METAL HYDRIDE COMPLEXES [Pg.150]

Dihydrogen Bonds Principles, Experiments, and Applications, By Vladimir i. Bakhmutov Copyright 2008 John Wiley Sons, inc. [Pg.150]

The situation becomes more complicated in CH2CI2 solutions. For example, the v(OH) regions in the IR spectra, recorded for 1 1 mixtures of ReH2(CO)(NO) (PR3)2 and (CF3)3COH, show the red frequency v(OH) shifts of 243 to 370 cm . It is obvious that the proton donor participates in intermolecular hydrogen [Pg.153]

The resnlts of DFT calcnlations performed for the model system ReH2(PH3)2 (N0)(C0)-H20 in a 1 1 ratio have revealed intermolecular interactions with all [Pg.154]

It is seen that the DFT calculations closely reproduce the tendencies observed experimentally. [Pg.155]

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