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Interfacial double layer phenomena

INTERFACIAL (DOUBLE LAYER) PHENOMENA 7.2 The electrode double layer... [Pg.145]

Experimentally, the electrical double-layer affect is manifest in the phenomenon named electrocapillarity. The phenomenon has been studied for many years, and there exist thermodynamic relationships that relate interfacial surface tension between electrode and electrolyte solution to the structure of the double layer. Typically the metal used for these measurements is mercury since it is the only conveniently available metal that is liquid at room temperature (although some work has been carried out with gallium. Wood s metal, and lead at elevated temperature). [Pg.45]

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