Figure 5.3 Schematic representation of a non-planar scale-alloy interface resulting from rate control by alloy interdiffusion. |

There are also other effects, which cannot be incorporated easily in the Poisson-Boltzmann formalism, such as the non-planarity of the interface, its thermal fluctuations, the charge fluctuations and so on. [Pg.385]

Use as coordinates the points halfway between the interface of adjacent elements, calculating the variation of concentration with time at these points. In this case there is no problem with the positioning of the electrode surface, as it is at the edge of a box. The simulation formulae are the same. This method can be particularly advantageous for non-planar electrodes as it is not necessary to decide on the three-dimensional shape of the elements only the position of the points matters. [Pg.413]

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