Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Integral electrosorption

The Integral Electrosorption Valency of Metal-Supported Thiol... [Pg.355]

No more than the slopes do they contain the electrosorption Gibbs energy. The surface pressure is experimentally accessible by Integration of the Gibbs equation dy = -Xjr d/i. The fact that some components are dubbed "charge determining" does not matter provided the sum Is taken over electroneutral components. This Is our choice, not that of thermodynamics which Is model-free. In practice this means that the r.h.s. of. for instance (3.12.4b( Is Integrated from the pristine surface at the p.z.c. to the final condition, determined by the final values of a°. cr and r. The surface pressure is a function of state, therefore... [Pg.440]

The integration constant denotes the electrosorption valency of a hypothetical... [Pg.54]

Figure 4.31 Determination of the electrosorption valency for Pb UPD on Ag(lll) by adsorbed charge (determined by integration of the cyclic voltammogram in Figure 4.27) versus adsorbed mass shown in Figure 4.30. The electrosorption valency is zy = 2. (Reproduced with permission from Ref. [60], 1978, Elsevier.)... Figure 4.31 Determination of the electrosorption valency for Pb UPD on Ag(lll) by adsorbed charge (determined by integration of the cyclic voltammogram in Figure 4.27) versus adsorbed mass shown in Figure 4.30. The electrosorption valency is zy = 2. (Reproduced with permission from Ref. [60], 1978, Elsevier.)...
See other pages where Integral electrosorption is mentioned: [Pg.328]    [Pg.357]    [Pg.328]    [Pg.357]    [Pg.328]    [Pg.221]    [Pg.137]   


SEARCH



Electrosorption

© 2024 chempedia.info