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Insertion reactions tetracyanoethylene

In the reaction of IrH(CO)(PPh3)3 with tetracyanoethylene (tcne) one molecule of tcne inserts into the iridium-hydrogen bond and a second molecule of tcne co-ordinates 7T-wise to the metal to give the product... [Pg.295]

Sulphur inserts into the vinyl-tin bond, as does tetracyanoethylene into the Sn—S bond of MeaSnSPh. A reinvestigation of the reaction of Mel with Mes-SnSMe shows MeaS+I and MegSnl to be the only products isolated. Aryl-... [Pg.163]

Reaction of [Cp RhCl2]2 with (2,6-dimethoxyphenyl)diphenylphosphine (mdmpp) gave Cp RhCl2(mdmpp-/ ) and Cp"RhCl(mdmpp-P,0), depending on the reaction conditions. Treatment of the first compound with NaPF formed the O-coordinated complex, [Cp"RhCl(mdmpp-P,OMe)](PF6)." Complex Cp"RhCl(mdmpp-P,0) readily reacted with tetracyanoethylene (tcne) or 7,7,8,8,-tetracyano-p-quinomethane (tcnq) to form the 1 1 adducts Cp RhCl(mdmpp-P,0)(tcne) 187 and Cp RhCl(mdmpp-P,0)(tcnq) derived from insertion of cyanoolefins into the... [Pg.159]

See other pages where Insertion reactions tetracyanoethylene is mentioned: [Pg.69]    [Pg.71]    [Pg.255]    [Pg.279]    [Pg.419]    [Pg.331]    [Pg.1101]    [Pg.295]    [Pg.331]    [Pg.1101]    [Pg.4555]    [Pg.5292]    [Pg.6476]    [Pg.416]    [Pg.375]    [Pg.238]    [Pg.346]    [Pg.228]   
See also in sourсe #XX -- [ Pg.71 ]



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Insertion reactions

Tetracyanoethylene, reactions

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