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Insertion Reactions miscellaneous

Organic isocyanates and isothiocyanates as well as nitric oxide insert similady (412). Carbon monoxide inserts to yield very stable acyltitamums (412,413). Miscellaneous Reactions of CpfTi Derivatives. Coupling of fluxional pentadienide ion with allyl bromide is regiospecificatly catalyzed by Cp2TiCl2 (414,415). In contrast, cuprous chloride gives the linear triene ... [Pg.160]

Miscellaneous Reactions. Diazomethane has been shown to react with vinylsilanes derived from a. -unsaturated esters to provide the corresponding allylsilane by insertion of CH2 into the C-Si bond (eq 49). The reaction has been shown to be stereospecific, with c/s-vinylsilane providing cts-allylsilanes however, the mechanism of the reaction has not been defined. Diazomethane has also been used in the preparation of trimethyloxoirium salts. Treatment of a solution of dimethyl ether and trinitrobenzenesul-fonic acid with diazomethane provides trimethyloxonium trini-trobenzenesulfonate, which is more stable than the fluoroborate salt. ... [Pg.150]

See other pages where Insertion Reactions miscellaneous is mentioned: [Pg.211]    [Pg.401]    [Pg.323]    [Pg.2240]    [Pg.97]    [Pg.377]    [Pg.160]    [Pg.295]    [Pg.251]    [Pg.364]    [Pg.215]    [Pg.212]    [Pg.215]    [Pg.143]    [Pg.143]    [Pg.215]    [Pg.531]    [Pg.373]    [Pg.339]    [Pg.312]    [Pg.31]    [Pg.280]    [Pg.10]   
See also in sourсe #XX -- [ Pg.212 ]



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Insertion reactions

Miscellaneous reactions

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