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Insertion of CO2 into E-X Bonds

Abstract This chapter deals with the insertion reactions of carbon dioxide (CO2) into E-X bonds, where E and X represent several different (sets of) atoms, such as M-H, M-OH, M-C, M-OR, M-O2, M-N, M-P, C-C, C-N, Si-H, and M-M (M = metal). Such reactions are relevant to catalysis for the formation of new bonds in which CO2 may be implied (C-C bonds or C-E bonds) and thus to the conversion of CO2 into added-value chemicals. The insertion product can be thermodynamically and kineticaUy stable or labile, offering in the latter case the opportunity of a catalytic path. [Pg.85]


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Insertion of CO2 into

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