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Influence of shear rate on induction period in oligomer curing

The rate of heat generation in shear flow is determined by the power of the work done this is the product of the shear rate and the shear stress. The resulting temperature change can be expressed as  [Pg.73]

Then we can rewrite Eq. (2.75) by replacing B with the expression from Eq. (2.76)  [Pg.74]

74) and (2.77) give us the principal solution of the problem being discussed, i.e., it is possible to calculate T(t) for different shear rates and then to find the upper limit of the integral in Eq. (2.77) for these rates. The solution becomes clearer if we choose dimensionless variables and transform Eqs. (2.74) and (2.77) into dimensionless form. Let us introduce a dimensionless temperature 0 such that  [Pg.74]

The dimensionless time x and dimensionless non-isothermal induction period x are written as follows  [Pg.75]

Two additional dimensionless values connected with the activation energies are also used  [Pg.75]




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Cure rate

Curing oligomers

Curing period

Induction curing

Induction period

Inductive curing

Influence of Shear Rate

Rate of cure

Shear rates

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