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Indium-mediated difluoroallylation

Indium mediates the coupling of a,a-difluoroallyl carbanion with aldehydes, to give geuz-difluorohomoallyl alcohols.89 hi contrast to many comparable allylations of carbonyl compounds, ketones do not react. [Pg.17]

Indium-mediated coupling of aldehydes with 3-bromo-3,3-difluoropropene occurs selectively at the gem-difluorocarboii which exhibits a,a-difluoroallyl carbanion behaviour.89... [Pg.341]


See other pages where Indium-mediated difluoroallylation is mentioned: [Pg.263]    [Pg.263]   
See also in sourсe #XX -- [ Pg.63 ]

See also in sourсe #XX -- [ Pg.63 ]




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Difluoroallylation

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