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Indium halides, carbene complexes

A mixed indium hydride halide complex, (l) InH2Cl (29) has been prepared from the 1 1 reaction of [InH2Cl(NMe3) ] with carbene (1) (R = Mes, R = H), as shown in Scheme iP The structure of (29) is monomeric with the geometry at the In center close to tetrahedral. The In-C distance (2.244(6) A) is similar to those observed in (28) (2.200(7) A) and (25) (2.253(5) A). A related mixed gallium hydride iodide complex (1) GaH2l (30) has been isolated from the reaction of (26) with GaT, with concomitant deposition of galhum metal. Complex (30) is isostructural with the related indium complex (29) and has a Ga-C bond distance of 2.022(4) A. [Pg.5770]

See other pages where Indium halides, carbene complexes is mentioned: [Pg.408]    [Pg.427]    [Pg.430]    [Pg.5769]    [Pg.5772]    [Pg.5773]    [Pg.5768]    [Pg.5771]    [Pg.5772]    [Pg.10]    [Pg.13]    [Pg.210]    [Pg.51]    [Pg.428]    [Pg.1732]    [Pg.5771]    [Pg.5771]    [Pg.1731]    [Pg.5770]    [Pg.5770]    [Pg.11]   
See also in sourсe #XX -- [ Pg.9 , Pg.10 ]

See also in sourсe #XX -- [ Pg.9 , Pg.10 ]



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