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Incoherent transport

For displacements shorter than the mean pore dimension, (z2) < a, where flow velocities tend to be spatially constant and homogeneously distributed, Brownian diffusion is the only incoherent transport phenomenon that contributes to the hydrodynamic dispersion coefficient. As a direct consequence, the dispersion coefficient approaches the ordinary Brownian diffusion coefficient,... [Pg.220]

In the case of the inelastic/incoherent transport regime, the phonon and the electron-phonon (e-ph) coupling term Hph and He.ph, respectively) should be added to the molecular Hamiltonian ... [Pg.328]

Charge transport is an incoherent random walk described by a generalized... [Pg.519]

The experiments just discussed made it clear that the motion of the hole on the series of As represents a different mechanism of transport than tunneling. Giese [13] and Bixon and Jortner [18] suggested that this mechanism is incoherent hopping of the hole between neighboring bases. This means that the hole wavefunction is Hmited to one base. The wavefunctions of the remaining electrons on that base would of course be distorted by the presence of the hole. Thus in this view of the transport process the base on which the hole sits could be called a molecular polaron, or a small polaron because it is limited to one site. [Pg.76]

In addition to measurements of how much and what type of chemical species are present, modification of the MR experiment allows us to identify the physical state of a given species (e.g., gas, liquid, gel, and solid) and to quantify temperature and any incoherent and/or coherent transport processes within the system. By integrating any of these measurements into an imaging experiment, we can spatially map these quantities or exploit the effect of these characteristics on the magnitude or frequency of the MR signal to preferentially observe sub-populations of spins within the system. In this latter application we are exploiting the so-called contrast mechanisms in the image acquisition. These concepts are illustrated in Sections II.B II.D. [Pg.13]

So far, we have tacitly assumed that the stresses were applied externally. However, stresses which are induced by local changes in component concentrations and the corresponding changes in the lattice parameters during transport and reaction are equally important. These self-stresses can strongly influence the course of a solid state reaction. Similarly, coherent, semicoherent, and even incoherent interfaces during heterogeneous solid state reactions are sources of (local and nonlocal) stress. The... [Pg.331]

A general term for the entire layer or mantle of fragmental and loose, incoherent, or unconsolidated rock material, of whatever origin (residual or transported) and of a much varied character, that nearly everywhere forms the surface of the land and overlies or covers the more coherent bedrock. It includes rock debris (weathered in place) of all kinds, volcanic ash, glacial drift, alluvium, loess and aeolian deposits, vegetal accumulations, and soils. [Pg.1495]

A further factor which affects the shape of a resonance line is the transport of resonance radiation through the. parent gas. Milne s early theory of self-absorption by the imprisonment of resonance radiation has been revised by Holstein (3) and Bichermau (4), taking into account the incoherent scattering of resonance photons. Furthermore, Walsh (" ) has extended the imprisonment lifetime calculation for cases where Doppler and collision broadening of the resonance line are simultaneously present, and in addition this author has examined the complications caused by the, hfs. The line shape, linewidth, and other properties of self-absorbed lines hare been discussed recently bv Tako (6), who summarizes the various effects of self-absorption as follows ... [Pg.216]


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See also in sourсe #XX -- [ Pg.220 ]




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