Immittance spectroscopy

Impedance spectroscopy is a well-established technique in electrochemistry, and it has been the topic of numerous articles and books. It is actually a subset of a broader category of spectroscopy that includes dielectric and conductance responses. All three terms (impedance, conductance, and dielectric response) are intimately related and are grouped under the general heading of immittance spectroscopy by MacDonald and Johnson [1]. For further detailed information on the various applications of immittance spectroscopy, the reader is directed to Ref. 1-4. 

Some authors have used the designation modulus spectroscopy to denote small-signal measurement of M vs. v or co. Clearly, one could also define admittance and dielectric permittivity spectroscopy. The latter is just another way of referring to ordinary dielectric constant and loss measurements. Here we shall take the general term impedance spectroscopy to include aU these other very closely related approaches. Thus IS also stands for immittance spectroscopy. The measurement and use of the complex (< ) function is particularly appropriate for dielectric materials, those with very low or vanishing conductivity, but aU four functions are valuable in IS, particularly because of their different dependence on and weighting with frequency. 

CHARACTERIZATION OF THE ELECTRICAL RESPONSE OF HIGH RESISTIVITY IONIC AND DIELECTRIC SOLID MATERIALS BY IMMITTANCE SPECTROSCOPY... 

Immittance — In alternating current (AC) measurements, the term immittance denotes the electric -> impedance and/or the electric admittance of any network of passive and active elements such as the resistors, capacitors, inductors, constant phase elements, transistors, etc. In electrochemical impedance spectroscopy, which utilizes equivalent electrical circuits to simulate the frequency dependence of a given elec-trodic process or electrical double-layer charging, the immittance analysis is applied. 

The immittance analysis can be performed using different kinds of plots, including complex plane plots of X vs. R for impedance and B vs. G for admittance. These plots can also be denoted as Z" vs. Z and Y" vs. Y, or Im(Z) vs. Rc(Z), and Im( Y) vs. Re( Y). Another type of general analysis of immittance is based on network analysis utilizing logarithmic Bode plots of impedance or admittance modulus vs. frequency (e.g., log Y vs. logo)) and phase shift vs. frequency ( vs. log co). Other dependencies taking into account specific equivalent circuit behavior, for instance, due to diffusion of reactants in solution, film formation, or electrode porosity are considered in - electrochemical impedance spectroscopy. Refs. [i] Macdonald JR (1987) Impedance spectroscopy. Wiley, New York [ii] Jurczakowski R, Hitz C, Lasia A (2004) J Electroanal Chem 572 355... 

---