Imine formation coordination polymerization

Note the most interesting examples. In particular, as ZnCh is added, we can observe an accelerated radiation polymerization of allyl acetate and allylamine by 6 and 30 times, respectively. When MX complexes include conventional monomers, the polymerizations are also typical in the case of ZnCl2. The same is observed for C0CI2, NiCU, and PdCE complexes with ethylene and triethylene imines and their derivatives (ML Cl2 witii = 1 to 4). Owing to the formation of a coordinate bond, these complexes are distinguished by a rearrangement of the electronic density at the atoms and bonds of the heterocycle, with the result that the ring stress increases appreciable (e.g. for ethylene imine by 42 kJ mol ) [78]). 

---