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Imidazole-4,5-diones, tautomerism

Imidazole-4,5-dicarboxylic acids, coupling, 5, 403 decarboxylation, 5, 434 1-substituted synthesis, 5, 468 synthesis, 5, 362, 402, 484 Imidazole-4,5-dione, l-alkyl-2-phenyl-synthesis, 5, 129, 479 Imidazole-2,4-diones tautomerism, 5, 370 Imidazole-4,5-diones tautomerism, 5, 370 Imidazole-2,4-dithione, 5,5-diphenyl-tautomerism, 5, 370 Imidazole-2,4-dithiones tautomerism, 5, 370 Imidazolepropanol synthesis, 5, 486 Imidazoles accelerators epoxy resins, 1, 407... [Pg.655]

Cases in which more than one tautomerizable substituent are present in the imidazole ring are common, but tautomerism studies of such compounds are less so. Work on the hydantoins (imidazolidine-2,4-diones) is not at all definitive UV and IR studies suggest the dioxo form (78), but evidence for the existence of other tautomeric structures (79,80) is not convincing (Scheme 26). ImidazoIidine-4,5-diones also exist as the dioxo forms. NMR studies show that the 2-benzyl derivatives must exist in solution as the NH form (81 R = H, Me), and the methoxy derivatives, similarly, are NH (82) rather than OH (83) derivatives (Scheme 26). [Pg.370]


See other pages where Imidazole-4,5-diones, tautomerism is mentioned: [Pg.21]    [Pg.474]    [Pg.474]    [Pg.100]    [Pg.150]   


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