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II Tetraphenylborate

The complex [(PEt3)2HPt( i-H)2Pt(PEt3)2] [BPh4] is a white, crystalline, air-stable solid that melts with decomposition at I25°C. It is soluble in acetone and dichloromethane and its solutions are air stable. [Pg.35]

Infrared-active (Pt—H) vibrations are observed as follows v,p,i i,= 2150 cm (m). Two weak, very broad absorption bands between 1550 and 2000cm are probably due to Pt—vibrations. [Pg.35]

A comprehensive set of NMR parameters for this compound, as well as figures of the spectra, have appeared elsewhere.  [Pg.35]

As for the previous compound, the characterization of this product is most easily carried out through its PNMR spectrum, which shows two central multiplets, flanked by their respective Pt satellites, with the following parameters obtained for acetone-de solutions d,pi, 24.2, Jp,i,p2 = 2540 Hz 5,p2i 20.8, Jp,2,p2 = 2741 Hz. The main features of the H NMR spectrum are two sets of multiplets centered as follows i, i, —4.93 and 5,n2, —3.55. [Pg.36]

DI-p-HYDRIDO-HYDRIDOTETRAKIS(TRIPHENYL-PHOSPHINE)DIPLATINUM(II) TETRAPHENYLBORATE(l - )... [Pg.36]

Hills A, Hughes DL, Jimenez-Tenorio M, Leigh GJ, Rowley AT. Bis[l,2-bis (dimethylphosphino) ethane] dihydrogenhydridoiron(II) tetraphenylborate as a model for the function of nitrogenases. J Chem Soc Dalton Trans. 1993 3041-3049. [Pg.370]

C33H38BN3NiS3, (Dimethylthiocarboxamido)(dimethylamino(dimethyldi-thiocarbamato)carbene)nickel(II) tetraphenylborate, 43B, 1011 C33Hft7BNgPt, Chugaev s red salt, 39B, 576... [Pg.405]

C60H76B2N1 Ni2 f Di-M azido-bis(2,2, 2"-triaminotriethylamine)dinic kel(II) tetraphenylborate, 41B, 962 CeoHe2B2NeNi03S3, Tris(ethylenediamine)nickel(11) tetraphenylborate - tris(dimethyl sulfoxide), 44B, 823 Ce 2H7 6B2CU2N10 f Bis(cyano-(2,2 ,2"-triaminotriethylamine)copper(II)) bis(tetraphenylborate), 40B, 817... [Pg.478]

Cs 1H4 5Cli,N3P2Pt, cis-Chlorobis( triphenylphosphine) - (1,3-di-p-tolyl-triazenido)platinum(II) chloroform solvate, 42B, 874 Cs1H4 5N3OP2RU, Hydrido(1,3-di-p-tolyltriazenido)bis(triphenylphos-phine)ruthenium(II) carbonyl, 42B, 874 Cs iHi, 9BF N2P2Pt, trans Hydrido(acetone phenylhydrazone)bis(triphen-ylphosphine)platinum(lI) tetrafluoroborate benzene, 43B, 1343 CsiH62AsBNnNiS, Isothiocyanato-(N,N-bis-(2-(diethylamino)ethyl)-2-(diphenylarsino)ethylamine-N,N,N)-nickel(II) tetraphenylborate,... [Pg.561]

CgeHe7BC0NO3P3S 0.5 CH2CI2, (Ethylsulfito)(tris(2-diphenylphos-phinoethyl)amine)cobalt(II) tetraphenylborate - 0.5 methylene chloride, 44B, 1049... [Pg.616]

C66H5gBBrCoOP3, Bromocarbonyl-1,1,1-tris(diphenylphosphinomethyl) ethanecobalt (II ) tetraphenylborate, 46B, 1307 Cs sHe 2BBrFePi, Bromo(tr is (2-dipheny Iphosphi noethyl )phosphine) iron-(II) tetrafluoroborate, 44B, 1079... [Pg.647]

Cg gHg 3BFeP4S, Thiolo(tris(2-diphenyIphosphinoethy1)phosphine)iron-(II) tetraphenylborate, 43B, 1473... [Pg.647]

CggHg3BNiP, S, Thiolo(tris(2-diphenylphosphinoethyl)phosphine)nickel-(II) tetraphenylborate, 42B, 1000 43B, 1473 Cg gHg 2B2Ni,Oi 2p Ru, trans-Bis (acetone hydrazone)tetrakis( trimethyl-phosphite) rutheniumdl) bis(tetraphenylborate), 40B, 1066 CssHg2Fe2NftNa20i8 2 Sodium di(M diphenylphosphido)-bis(tricarbonyl-iron) 1,l0-diaza-4,7,13,16,21,24-hexaoxabicyclo[8.8.8]hexacosane, 45B, 1384... [Pg.647]

Cy 3HS0CI4P4RU2S, Thiocarbonylbis(triphenylphosphine)ruthenium-tri-/n-chloro-chlorobis(triphenylphosphine)ruthenium, 40B, 1068 Cy 3Hy0BC0INP3, Iodo(tris-(2-diphenylphosphinoethyl)amine)cobalt(II) tetraphenylborate toluene, 41B, 1214 Cy4H6oA92N2P4S2 r ThiocyanatobisUriphenylphosphine)siIver(I), 39B,... [Pg.648]

Cs uHy yBNNiPaSn, (TriphenyIstannyl)(tris(2-diphenylphosphinoethyl)am-ine)nickel(II) tetraphenylborate, 43B, 1477 C8aH8 Cl2Cu202P6f Dichlorotris-(1,2-bis(diphenylphosphino)ethane)di-copper(l) bisacetone, 38B, 1054... [Pg.649]

C1oeHi01ASgBCoa, Tri-M hydrido-bis(1,1,1-tris(diphenylarsinomethyl)-ethanecobalt(II)) tetraphenylborate, 41B, 1228... [Pg.650]

Cl42H11H1B2CO2O6P6, Di-M-hydroxo-bis(1,1,1-tris(diphenylphosphino-methyl)ethane)dicobalt (II) tetraphenylborate acetone solvate, 41B, 1229... [Pg.650]

Coles SJ, Edwards PG, Fleming JS et al (1995) Triphosphorus macrocycle complexes of divalent group 6 transition metals. Crystal structure of bromotricarbonyl-[l,5,9-tris(isopropyl)-l,5,9-triphosphacyclododecane]-molybdenum(II) tetraphenylborate. J Chem Soc Dalton Trans 4091 097... [Pg.436]

See other pages where II Tetraphenylborate is mentioned: [Pg.177]    [Pg.136]    [Pg.138]    [Pg.139]    [Pg.70]    [Pg.32]    [Pg.34]    [Pg.21]    [Pg.24]    [Pg.78]    [Pg.32]    [Pg.34]    [Pg.36]    [Pg.721]    [Pg.315]    [Pg.413]    [Pg.478]    [Pg.478]    [Pg.478]    [Pg.478]    [Pg.560]    [Pg.562]    [Pg.643]    [Pg.643]    [Pg.648]    [Pg.310]    [Pg.136]    [Pg.138]   


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