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Idopyranoses, structure

With such a sequence in mind, for a product (m.p. 70-71°, [a]D—63.8°),2 of the p-toluenesulfonylation of l,6-anhydro-/3-D-idopyranose, the structure of 1,6-an-hydro-2-O-p-tolylsulfonyI-R-D-idopyranose may be proposed. The supposed structure of 6-O-p-tolylsulfonyl-D-idose for this compound 23 is, with respect to the optical rotation, improbable the 1,6-anhydride bond should be stable under the conditions of p-toluenesulfonylation. [Pg.82]

Using chair representations, write the structure of a-d-allopy ranose, P-d-altropyranose, a-d-gulopyranose, p-d-idopyranose, and a-d-talopyranose. [Pg.1432]


See other pages where Idopyranoses, structure is mentioned: [Pg.171]    [Pg.181]    [Pg.171]    [Pg.181]    [Pg.149]    [Pg.153]    [Pg.161]    [Pg.144]    [Pg.162]    [Pg.468]    [Pg.171]    [Pg.189]    [Pg.310]    [Pg.32]    [Pg.39]   
See also in sourсe #XX -- [ Pg.44 ]




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Idopyranose

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