Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

I.HMDS

Cobalt complexes with 14-membered tetraazamacrocyclic ligands have been investigated and successfully employed as catalysts for electrochemical and photochemical reduction of C02 and H20.230 One such complex low-spin [Co(I)HMD] + (HMD = 5,7,7,12,14,14,-hexamethyl-l,4,8,ll-tetraazacyclotetradeca-4,ll-diene (hex-amethylcyclam)) reacts with C02 in H20 and in CH3CN to form the N-rac-[CoHMD(C02)]+ species which is sufficiently stable in dry CH3CN and in a C02... [Pg.50]

Reagents i, HMDS, BuLi then TbdmsQ ii, heat, toluene iii, KF then hfel... [Pg.360]

See other pages where I.HMDS is mentioned: [Pg.48]    [Pg.991]    [Pg.952]    [Pg.921]    [Pg.836]    [Pg.101]    [Pg.134]    [Pg.836]    [Pg.51]    [Pg.275]    [Pg.275]    [Pg.446]    [Pg.368]    [Pg.369]    [Pg.370]    [Pg.370]    [Pg.378]    [Pg.431]    [Pg.446]    [Pg.114]    [Pg.431]    [Pg.446]    [Pg.269]    [Pg.102]    [Pg.205]    [Pg.163]   
See also in sourсe #XX -- [ Pg.216 , Pg.236 ]



SEARCH



HMDS

© 2024 chempedia.info