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Hyperconjugation has a profound effect on structure and stability of cyclohexyl cations. An elegant study combined theoretical results with experimental data to confirm that different hyperconjugative stabilization patterns lead to the formation of two equilibrating conformers of the 1-methyl-1-cyclohexyl cation where the carbocation p-orbital is oriented either pseudoaxiaUy or pseudoequatoriaUy. [Pg.124]

Stabilizing hyperconjugative effects in the axial and equatorial hyperconjomers of cyclohexyl [Pg.124]

See other pages where Hyperconjomers of cyclohexyl cations is mentioned: [Pg.124]