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Hynes model

Figure 2. Plot of observed frequency factors versus those calculated according to Hynes Model. (298K) Open circles indicate the calculated values taking account of the multiple relaxation of alcohols. Figure 2. Plot of observed frequency factors versus those calculated according to Hynes Model. (298K) Open circles indicate the calculated values taking account of the multiple relaxation of alcohols.
These and similar results have been interpreted as confirmations of the Grote-Hynes model as a valid physical theory of liquid phase reactions, and, relatedly, of frequency-dependent friction as a valid concept for liquid phase chemistry. This interpretation is spurious. Actually the result Kgh( ) Kmd(T ) shows only that for the systems of Table III the decision to react is made near the barrier top. [Pg.203]

See other pages where Hynes model is mentioned: [Pg.73]    [Pg.94]    [Pg.429]    [Pg.201]    [Pg.202]    [Pg.178]    [Pg.234]    [Pg.335]   
See also in sourсe #XX -- [ Pg.429 ]



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Hynes

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