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Hydroxylation with thallium acetate

Hydroxylamines, V-substituted, 58,108 Hydroxylation with thallium(l) acetate,... [Pg.118]

STEREOSELECTIVE HYDROXYLATION WITH THALLIUM(I) ACETATE AND IODINE trans- AND cis-l,2-CYCLOHEXANEDIOLS... [Pg.220]

Gamble, R. G., Rutledge, P. S. Stereoselective hydroxylation with thallium(l) acetate and iodine trans- and cis-1,2-cyclohexanediols. Org. Synth. 1980, 59, 169-176. [Pg.656]

Vicinal iodo carboxylates may also be prepared from the reaction of olefins either with iodine and potassium iodate in acetic acid/ or with N-iodosuccinimide and a carboxylic acid in chloroform. " A number of new procedures for effecting the hydroxylation or acyloxylation of olefins in a manner similar to the Prevost or Woodward-Prevost reactions include the following iodo acetoxylation with iodine and potassium chlorate in acetic acid followed by acetolysis with potassium acetate reaction with iV-bromoacetamide and silver acetate in acetic acid reaction with thallium(III) acetate in acetic acid and reaction with iodine tris(trifluoroacetate) in pentane. ... [Pg.88]

Since silver salts are expensive, other cheaper reagents have been sought which can bring about the same type of conversion, and the iodine- tassium iodate- tassium acetate combination has been found to provide a useful alternative. Thallium(I) acetate may be used in place of silver acetate in the Woodward procedure, and syn hydroxylation of steroidal alkenes with dialliumflll) acetate in acetic acid has been performed. ... [Pg.445]

See other pages where Hydroxylation with thallium acetate is mentioned: [Pg.513]    [Pg.291]    [Pg.1050]    [Pg.414]    [Pg.414]    [Pg.1751]    [Pg.24]    [Pg.234]    [Pg.152]    [Pg.106]    [Pg.405]   
See also in sourсe #XX -- [ Pg.59 , Pg.168 ]



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Hydroxyl acetates

With thallium acetate

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