5- Hydroxylamino-1,2,4-triazines, formation

Tiiazine A-oxides can be obtained by two general methods by direct oxidation of the parent 1,2,4-tiiazines with organic peracids, and by the formation of the A-oxide group of the 1,2,4-triazine ring by cyclization involving nitro, nitroso (isonitroso), or hydroxylamino groups. 

The metabolic fate of RDX was studied in a mixed culture incubated under methanogenic conditions. Analysis by HPLC confirmed the loss of RDX and the formation of mono-, di-, and trinitroso-RDX as transient biodegradation intermediates. An additional peak observed in the HPLC chromatogram was identified by LC-MS as hydroxylamino-dinitroso-l,3,5-triazine <2001ETC1874>. 

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See also in sourсe #XX -- [ , ]

See also in sourсe #XX -- [ , ]

See also in sourсe #XX -- [ , ]

See also in sourсe #XX -- [ , ]

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