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Hydroxyalkyl azides Schmidt reactions

Intermolecular Schmidt reactions of alkyl azides and hydroxyalkyl azides with cycloketones in the presence of a Lewis acid, lead to formation of iV-alkyl lactams and A-hydroxyalkyl lactams respectively in good yield. The synthesis of chiral lactams by an asymmetric Schmidt reaction has also been reported. ... [Pg.253]

Scheme 4.6 Tntermolecnlar Schmidt reactions using hydroxyalkyl azides. Scheme 4.6 Tntermolecnlar Schmidt reactions using hydroxyalkyl azides.
Variation 4 Asymmetric Schmidt Reaction of Ketones with Hydroxyalkyl Azides (Aube )... [Pg.358]

Schmidt Rearrangement Reactions with Alkyl Azides 201 Table 7.3 Reactions of hydroxyalkyl azides with ketones... [Pg.201]

Scheme 7.15 Asymmetric Schmidt reactions with a monosubstituted hydroxyalkyl azide... Scheme 7.15 Asymmetric Schmidt reactions with a monosubstituted hydroxyalkyl azide...
Rudy H, Cramer KE (1939) Uber den oxydativen Abbau des alloxan-2-dimethylatino anils zu 1-methyl benzimidazol. Chem Ber A 72(4) 728-744 Sahasrabudhe K, Gracias V, Furness K, Smith BT, Katz CE, Reddy DS, Aube J (2003) Asymmetric Schmidt reaction of hydroxyalkyl azides with ketones. J Am Chem Soc 125 (26) 7914-7922. doi 10.1021/ja0348896... [Pg.268]

See other pages where Hydroxyalkyl azides Schmidt reactions is mentioned: [Pg.161]    [Pg.386]    [Pg.670]    [Pg.192]    [Pg.205]   


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Azidation reaction

Azides, reactions

Hydroxyalkyl

Hydroxyalkyl azides

Hydroxyalkyl azides, Schmidt reaction ketones

Hydroxyalkylation

Hydroxyalkylations

Reactions hydroxyalkylation

Schmidt

Schmidt reaction

Schmidt reaction reactions

Schmidt reactions hydroxyalkyl azides with ketones

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