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Hydroxoaqua copper complex

A hydroxoaqua copper complex containing N, N, N, A -tetramethyl-1,2-diamino-ethane (250) is an excellent catalyst for the hydrolysis of sarin, O-isopropyl methylphosphonofluoridate (251), and diethyl p-nitrophenyl phosphate (252 R = Et). The mechanism of the reaction probably involves bound hydroxide attacking the phosphoryl group with concomitant electrophilic catalysis by copper. [Pg.80]


See also in sourсe #XX -- [ Pg.80 ]

See also in sourсe #XX -- [ Pg.80 ]

See also in sourсe #XX -- [ Pg.80 , Pg.98 ]




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