Hydrotris borate ligands cyclopalladated complexes

Organonickel derivatives also offer cases of the -coordination of the substituted hydrotris(pyrazol-l-yl)borate ligand. For the palladium and platinum complexes, the M(II) M(IV) (M = Pd, Pt) transformation is facile. Organopalla-dium chemistry offers a new type of agostic interactions, C—H Pd, where the C—H bond belongs to one of the pyrazolate rings. Cyclopalladation of various pyrazol-l-ylborates and -methanes does not modify their structure. 

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See also in sourсe #XX -- [ , ]

See also in sourсe #XX -- [ , ]

See also in sourсe #XX -- [ , ]

See also in sourсe #XX -- [ , ]

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