Hydrosulfido complexes types

Hydrosulfido complexes, 517 bonding, 519 reactivity, 519 structures, 519 synthesis, 518 types, 518 Hydroxamates metal complexes, 505-508 Hydroxamic acid, N-methyl-metal complexes, 507 Hydroxamic acid, phenyl-metal complexes stability, 506 Hydroxamic acids... 

The complex chemistry of the hydrosulfido ligand has emerged during the last decade. The bonding versatility of this ligand is immediately obvious from Figure 1, and for each of the types A-C examples have been reported in the literature. This flexibility is mainly due to the fact that the SH group can act as a one-, three- or five-electron donor. However, polynuclear systems with and... 

The synthesis of the cubane-type sulfido cluster (TiCp)[Ru(C5Me5)]3(//3-S)4 (Scheme 707) is described by crossed condensation of the two hydrosulfido-bridged binuclear complexes (TiCp2)(//-SH)2[Ru(C5Me5)Cl] and [Ru(C5Me5)Cl]2(/x-SH)2.1780... 

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