Hydrosulfido complexes reactivity

Hydrosulfido complexes, 517 bonding, 519 reactivity, 519 structures, 519 synthesis, 518 types, 518 Hydroxamates metal complexes, 505-508 Hydroxamic acid, N-methyl-metal complexes, 507 Hydroxamic acid, phenyl-metal complexes stability, 506 Hydroxamic acids... 

The pAT values of hydrosulfido complexes have never been investigated in detail, although a huge number of hydrosulfido complexes are known [40]. During our continuous study on the reactivities of coordinated dinitrogen, we have... 

Hydrosulfido complexes, which contain M-SH groups, can react by an additional pathway unavailable to metal-thiolate complexes. Hydrosulfido complexes can react by cleavage of the S-H group to generate metal-sulfido complexes. The synthesis and reactivity of sulfido complexes are described in Qrapter 13 (metal-ligand multiple bonds). 

Gerbino DC, Hevia E, Morales D, et al. A new reactivity pattern of low-valent transition-metal hydroxo complexes straightforward synthesis of hydrosulfido complexes via reaction with carbon disulfide. Chem Commun. 2003 328—329. 

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