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Hydrosilylation second-generation catalyst

This second-generation catalyst rapidly showed its value and, after a small optimization of the reaction conditions, outstanding results were obtained in the hydrosilylation of 1-octyne (31) with bis(trimethylsilyloxy)methylsilane (3) (Scheme 5.13) [35]. The outcome of the reaction revealed it to be rather sensitive to catalyst loading and a significant decrease in selectivity was observed when... [Pg.162]

Scheme 5.13 Optimized conditions for the hydrosilylation of 1-octyne (31) by MCiM (3) using second-generation catalyst 45. Scheme 5.13 Optimized conditions for the hydrosilylation of 1-octyne (31) by MCiM (3) using second-generation catalyst 45.
Having optimized the conditions, the scope and limitations of this second-generation catalyst 45 was investigated (Table 5.7) [35]. The hydrosilylation of... [Pg.163]

See other pages where Hydrosilylation second-generation catalyst is mentioned: [Pg.162]    [Pg.474]    [Pg.667]    [Pg.1758]    [Pg.209]    [Pg.407]    [Pg.409]    [Pg.181]    [Pg.1758]    [Pg.723]    [Pg.160]    [Pg.56]    [Pg.699]    [Pg.438]    [Pg.438]    [Pg.6]    [Pg.518]    [Pg.72]   
See also in sourсe #XX -- [ Pg.138 , Pg.139 ]



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Catalyst generations

Hydrosilylation catalysts

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