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Hydrosilane, polymethylhydrosiloxane PMHS

Asymmetric reduction of a, /I-unsaturated esters, lactones or lactames can be effected with copper-hydride catalysts and chiral phosphanes such as various BINAP related compounds in excellent yields and enantioselectivities (equation 23). As the hydrosilane component, polymethylhydrosiloxane (PMHS) is frequently used for this reaction. [Pg.1652]


See other pages where Hydrosilane, polymethylhydrosiloxane PMHS is mentioned: [Pg.366]    [Pg.190]    [Pg.366]    [Pg.190]    [Pg.318]    [Pg.127]    [Pg.171]    [Pg.524]    [Pg.248]    [Pg.253]   
See also in sourсe #XX -- [ Pg.127 ]




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Hydrosilane

Hydrosilanes

PMHS

Polymethylhydrosiloxane

Polymethylhydrosiloxane (PMHS

Polymethylhydrosiloxanes

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