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Hydrophobic dissociation relationship with

Methylhydroxycarbene, MeC(OH), has been generated in one of the three reaction pathways of the collision-induced dissociation of protonated butane-2,3-dione.13 Its enthalpy of formation was found to be 16 4 kcalmol-1. Fluorophenoxycarbene (PhOCF) has been generated inside a hydrophobic hemicarcerand (1) by irradiation of the corresponding confined diazirine.14 Its reactivity (especially dimerization and reaction with water) was significantly lowered by the incarceration, allowing its persistence for days at room temperature. New (amino)(silyl)carbenes (2) have been generated and their structure-activity relationship studied. They showed behaviour similar to those of previously reported (amino)(alkyl)carbene.15... [Pg.132]

See other pages where Hydrophobic dissociation relationship with is mentioned: [Pg.448]    [Pg.564]    [Pg.231]    [Pg.211]    [Pg.106]    [Pg.192]    [Pg.5]    [Pg.74]    [Pg.61]    [Pg.105]    [Pg.426]    [Pg.439]    [Pg.160]   
See also in sourсe #XX -- [ Pg.202 ]



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Hydrophobic dissociation

Relationships with

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